格氏***,格林尼亚***,R-MgX
格氏***,又称格林尼亚***,是指法国化学家维克多·格林尼亚发现的烃基卤化镁(R-MgX)一类有机金属化合物,是一种很好的亲核***,在有机合成和有机金属化学中有重要用途。原理:由于镁原子直接和碳链相连,极化作用的结果是使邻近镁原子的那个碳原子呈负电性,使得这根C-Mg键***反应活性。为了保证格氏***不发生其他反应,反应一般在醚类溶剂里进行,常用的有***或四氢***。格氏***实现了由碳正向碳负的转化,具有重要的意义。应用:格式***在有机合成中能起三种不同的功能。一个是亲核***,这是***常见的功能;第二是作为碱使用,普通***卤化镁能产生相当于pka30左右的碱性,常常作为一种易得的强碱使用,常作为烯胺拔氢用碱;第三个功能是作为还原剂。西宝生物优选ACROS常用格式***,并提供***市场竞争力的价格,且大部分备有国内现货。产品编号中英文名产品规格CAS包装37738***化镁1MsolutioninTHF,AcroSeal75-16-1100mLMethylmagnesiumbromide800mL37733***化镁1.4Msolutionintoluene/THF,AcroSeal75-16-1100mLMethylmagnesiumbromide800mL18354***化镁3Msolutionindiethylether,AcroSeal75-16-1100mLMethylmagnesiumbromide800mL39112***化镁3.2Msolutionin2-MeTHF,AcroSeal75-16-1100mLMethylmagnesiumbromide800mL25256甲基氯化镁3M(22wt.%)solutioninTHF,AcroSeal676-58-4100mLMethylmagnesiumchloride800mL34728******化镁0.9Mintert-Butylmethylether,AcroSeal925-90-6100mLEthylmagnesiumbromide800mL21047******化镁0.9MsolutioninTHF,AcroSeal925-90-6100mLEthylmagnesiumbromide800mL34729******化镁3Msolutionindiethylether,AcroSeal925-90-6100mLEthylmagnesiumbromide800mL18353******化镁3.2Msolutionin2-MeTHF,AcroSeal925-90-6100mLEthylmagnesiumbromide800mL37728***氯化镁2.0MsolutioninTHF,AcroSeal925-90-6100mLEthylmagnesiumchloride800mL25257***氯化镁2.7M(25wt.%)solutioninTHF,AcroSeal925-90-6100mLEthylmagnesiumchloride800mL20939乙烯基***化镁0.7MsolutioninTHF,AcroSeal1826-67-1100mLVinylmagnesiumbromide800mL25259乙烯基氯化镁1.9M(16.5wt.%)solutioninTHF,AcroSeal3536-96-7100mLVinylmagnesiumchloride800mL43912***基***化镁0.5MsolutioninTHF,AcroSeal4301-14-8100mLEthynylmagnesiumbromide800mL38895***基氯化镁0.6MsolutioninTHF/Tolueue,AcroSeal65032-27-1100mLEthynylmagnesiumchloride800mL20845***化镁2Msolutionindiethylether,AcroSeal2234-82-4100mLPropylmagnesiumchloride800mL42678******化镁3Msolutionin2-Methyltetrahydrofuran,AcroSeal920-39-8100mLIsopropylmagnesiumbromide21285***氯化镁2.0MsolutioninTHF,AcroSeal1068-55-9100mLIsopropylmagnesiumchloride800mL38628***氯化镁-氯化锂1.3MsolutioninTHF,AcroSeal745038-86-2100mLsopropylmagnesiumchloride-lithiumchloridecomplex800mL39761环丙基***化镁0.5MsolutioninTHF,AcroSeal23719-80-4100mLCyclopropylmagnesiumbromide20953烯丙基***化镁1Msolutionindiethylether,AcroSeal1730-25-2100mLAllylmagnesiumbromide800mL20967***化镁1.7MsolutioninTHF,AcroSeal2622/5/1100mLAllylmagnesiumchloride800mL33168***化镁20wt%solutioninTHF/Toluene,AcroSeal693-04-9100mLn-Butylmagnesiumchloride800mL33166***基氯化镁25wt%solutioninTHF,AcroSeal15366-08-2100mLsec-Butylmagnesiumchloride33167***化镁1.7MsolutioninTHF,AcroSeal677-22-5100mLtert-Butylmagnesiumchloride800mL39430***化镁1.7Msolutionindiethylether,AcroSeal677-22-5100mLtert-Butylmagnesiumchloride800mL42739异丁基***化镁2Msolutionindiethylether,AcroSeal926-26-5100mLIsoutylmagnesiumbromide800mL20952***化镁2Msolutionindiethylether,AcroSeal5674/2/2100mLIsoutylmagnesiumchloride800mL43555戊基***化镁2Msolutionindiethylether,AcroSeal6393-56-2100mLPentylmagnesiumbromide800mL43621戊基氯化镁1.3MsolutioninTHF,AcroSeal693-25-4100mLPentylmagnesiumchloride800mL42745***化镁2.0Msolutionindiethylether,AcroSeal33240-34-5100mLCyclopentylmagnesiumbromide800mL20846环戊基氯化镁2Msolutionindiethylether,AcroSeal32916-51-1100mLCyclopentylmagnesiumchloride800mL42776***化镁0.8MsolutioninTHF,AcroSeal3761-92-0100mLHexylmagnesiumbromide800mL43468***化镁2MsolutioninTHF,AcroSeal44767-62-6100mLHexylmagnesiumchloride800mL37734环***化镁1.3MsolutioninTHF/Toluene,AcroSeal931-51-1100mLCyclohexylmagnesiumchloride800mL37741******化镁1MsolutioninTHF,AcroSeal100-58-3100mLPhenylmagnesiumbromide800mL17398******化镁2.8Msolutionindiethylether,AcroSeal100-58-3100mLPhenylmagnesiumbromide800mL39111******化镁2.8Msolutionin2-MeTHF,AcroSeal100-58-3100mLPhenylmagnesiumbromide800mL25258***氯化镁25wt%solutionintetrahydrofuran,AcroSeal100-59-4100mLPhenylmagnesiumchloride800mL377234-***基***化镁0.8MsolutioninTHF,AcroSeal352-13-6100mL4-Fluorophenylmagnesiumbromide800mL377374-***基***化镁2Msolutionindiethylether,AcroSeal352-13-6100mL4-Fluorophenylmagnesiumbromide800mL377404-***基***化镁1Msolutionindiethylether,AcroSeal873-77-8100mL4-Chlorophenylmagnesiumbromide800mL377254-***基***化镁1MsolutioninTHF/toluene,AcroSeal873-77-8100mL4-Chlorophenylmagnesiumbromide800mL377424-*********化镁1MsolutioninTHF,AcroSeal13139-86-1100mL4-Methoxyphenylmagnesiumbromide800mL38995***化镁1.5MsolutioninTHF,AcroSeal6921-34-2100mLBenzylmagnesiumchloride800mL更多相关产品,欢迎咨询:上海西宝生物科技有限公司电话:021-50272975/76/77/78杨露13512172575***:1916572322分机6221俞婵13817370083***:2457655304分机6512杨树彦13788987962***:1961275959分机6236传真:021-50272982E-mail:trade@lifesci9@MSN:lifesci9@Http://地址:上海市张江高科技园区毕升路299弄11#502)