ABSsurfacepretreatmentisnecessarytopretreattheplasticsurfacebeforepainting,inordertoimprovetheadhesionofthecoatingonthesurfaceoftheplasticandimprovetheappearanceoftheplastic.(1)whenannealedplasticABSisformed,itiseasytoforminternalstressandeasytocrackatthestressconcentrationaftercoating.Annealingorsurfacetreatmentcanbeusedtoeliminatestress.AnnealingtreatmentistoheattheABSplasticmoldingpartsbelowthethermaldeformationtemperature,thatis,60degreescentigrade,andheatpreservation2H.Inordertoreduceinvestmentinequipment,thewholesurfacetreatmentcanbeusedtoimprovethesurfacecondition.TheformulationandprocessofthewholesurfacetreatmentarelistedinTable1.Table1wholesurfacetreatmentformulaandprocessparameters/1water/3temperature/temperature/Croomtemperaturetreatmenttime/mi15-20(2)oilremovalABSplasticpartsareoftencontaminatedwithoil,handsweatanddemouldingagent,whichwillmaketheadhesionofthecoatingworse,thecoatingproducescracking,foamingandshedding.Oilremovalshouldbecarriedoutbeforecoating.ABSplasticpartsareusuallycleanedwithgasolineoralcoholandthenchemicaldegreasing.TheprocessformulaislistedinTable2.Table2theresidualalkalinesolutiononthesurfaceoftheworkpieceshouldbethoroughlycleanedaftertheprocessparametersofsodiumhydroxide(S/L)sodium50~70phosphate(S/L)20~30sodiumcarbonate(S/L)10~20surfaceactiveagent(S/L)5~10temperature/50~60treatmenttime/min10to15chemicaloil,andcleanedwithpurewater***,dryingordrying.(3)electricalanddustremovalplasticproductsareinsulators,andthesurfaceresistanceisgenerallyaround1013ohms,whichiseasytogeneratestaticelectricity.Aftercharged,itiseasytoadsorbtinydustintheairandsticktothesurface.Itisverydifficulttoremovedustfromelectrostaticadsorptionbygeneralblowingmethod.Highpressureionizedairflowhasgoodeffectinadditiontoelectrostaticprecipitator.*TPU685A10器材TPUˉT5275PA6中石化巴陵BL3350PP1148TCPOMFU2050PA663021G-30TPUˉ180（Mica）PA66A3UTPE德国胶宝TC6NYNTPU58201PP/2252E4TPEA1606PA6深圳东丽CM1011G15PPB200PPC/K-20UVR28PPˉ9060PP/N05G-00PP中石化燕山SP179PC/ABS德国科思创（拜耳）225C/ABS500S2LCPE6810FPBT江苏三房巷4308PA6VE35CPA12/SX90398/TPV8271-55PEI2100-7320PPˉ7575PPE旭化成640ZPP/PP-160UVTPU美国RONR172DEVA/30E75PˉD1153ˉPP/PHC31-81TPUˉ1090APP5E16SPCHPS6TPEˉ201EVA1850APVDF法国阿科玛HR761PA6V315ZH2.0PA11/BESNOP10TLPPˉTD218BFPBT基础创新塑料VX5011TPV3140NThecommonmethodsofchemicalmodificationare:oneisoneelementofthemodifiedresinmonomer,themodifiedmonomerisanother,graftcopolymerizationinthereactionkettleandanewcopolymer.Thesecondmethodistomodifythemodifiedresinasthemainrawmaterialbyincreasingthepolarelementintheresinmolecule.聚丙烯广泛用于塑料管材的生产，但PP是一种抗老化性能差的材料，为了PP的性能，通过化学改性发明了PP-B和PP-R树脂。Polypropyleneiswidelyusedintheproductionofplasticpipes,butPPisakindofpooranti-agingmaterial.InordertoimprovetheperformanceofPP,PP-BandPP-Rresinhebeeninventedbychemicalmodification.PP-B树脂是丙烯和的嵌段共聚物。合成丙烯-嵌段共聚物要用两个聚合反应釜PP-Bresinisablockcopolymerofpropyleneandethylene.TwopolymerizationreactorsforthesynthesisofpropyleneethyleneblockcopolymersPA66对许多溶剂具有抗溶性，但对酸和其它一些氯化剂的抵抗力较弱。PA66isresistanttomanysolvents,butislessresistanttoacidsandotherchlorinatedagents.工艺条件processconditi***干燥处理：如果加工前材料是密封的，那么就没有必要干燥。然而，如果储存容器被打开，那么建议在85℃的热空气中干燥处理。如果湿度大于0.2%，还需要进行105℃，12小时的真空干燥。熔化温度：260~290℃。对玻璃添加剂的产品为275~280℃。熔化温度应避免高于300℃。模具温度：建议80℃。模具温度将影响结晶度，而结晶度将影响产品的物理特性。对于薄壁塑件，如果使用低于40℃的模具温度，则塑件的结晶度将随着时间而变化，为了保持塑件的几何性，需要进行退火处理。***压力：通常在750~1250bar，取决于材料和产品设计。Drying:ifthematerialissealedbeforeprocessing,thereisnoneedtodry.However,ifthestoragecontainerisopened,itisrecommendedtodryat85Chotair.Ifthehumidityisgreaterthan0.2%,thevacuumdryingat105Cand12hoursisrequired.Meltingtemperature:260~290C.Theproductofglassadditiveis275~280C.Themeltingtemperatureshouldbeoidedabove300degreesC.Moldtemperature:recommended80degreesC.Themoldtemperaturewillaffectthecrystallinity,andthecrystallinitywillaffectthephysicalcharacteristicsoftheproduct.Forthin-walledplasticparts,ifthemoldtemperaturebelow40degreesisused,thecrystallinityoftheplasticpartswillchangewithtime.Inordertomaintainthegeometricstabilityoftheplasticparts,theannealingprocessisneeded.Injectionpressure:usuallyin750~1250bar,dependingonmaterialandproductdesign.***速度：高速（对于增强型材料应稍低一些）。高性能PC‖/ABSA2200合金材料具有高抗冲击、优良的耐候性和亚光效果，可应用于车载音响和DVD、汽车仪表板等部件。电镀级PC‖/ABSA2200MP具有杰出的电镀效果和良好的耐低温性能，可应用于汽车把手等电镀部件。Injectionspeed:highspeed(forenhancedmaterialshouldbeslightlylower).HighperformancePC/ABSA2200alloymaterialhashighimpactresistance,excellentweatherabilityandsublighteffect.Itcanbeusedinvehicleaudio,DVDsystem,vehicledashboardandothercomponents.ElectroplatedgradePC/ABSA2200MPhasexcellentelectroplatingeffectandgoodlowtemperatureresistance.Itcanbeappliedtoelectroplatingpartssuchascarhandles.注意事项：/PC‖塑料成型问题Note:/PCplasticsmoldingprocessproblem??产生原因及解决办法CausesandSoluti***??1、银丝1,silversilk??a、原材料受潮————干燥原料A,rawmaterialsaredampened-dryrawmaterials??b、树脂过热分解————减低成型温度B,superheateddecompositionofresin--reducingmoldingtemperature??c、螺杆压缩比小，背压不足————背压C,screwcompressionratiois***all,backpressureisinsufficient--increasebackpressure.??d、模温过低————加热模具D,lowmoldtemperature--heating??e、排气不良————模具分型面开排气槽Eandpoorexhaust--theexhaustmanifoldofthemoldpartingsurface*TPU685A10器材PPFR-170PCˉPCG-2205PP8620APCˉDX05477PP/E6AIBPBT420UPA6ˉLT5050ESPMMAMFM-405ASAG5130PA12瑞士EMSBE475PCDF004EPCWR5210R-7921PA6/K222-KWGV4ETFEEC6510(粉)PA6荷兰DK224-HG8PA6ˉV25H2.0LTˉPBT/5202/TPV/3190BPC/PC-6710PMMA1800ZPOM/M25LV/PBTKP213G45LLDPE美国陶氏2036PPA66ˉHK4920SNEVA/28-420PA6/BM-30ABS巴斯夫GP-35BKPA66RFL-36XXZPOM/FU2025/PPˉ5014LMATˉPA66ˉRX10408HEVAPA-541PC/303-15PPPGB601HPBJ356MO(LF)PC7100-15PPS油墨FZ1140PA6ˉPH0240APBT宝理7400FNCPP1040PA6ˉHFXˉ37LCP宝理S135VF2001PPS6165A6PA6BGZ-50/2KJ)