
PP EP540S ╮ PP EPKC10ZC
ABSsurfacepretreatmentisnecessarytopretreattheplasticsurfacebeforepainting,inordertoimprovetheadhesionofthecoatingonthesurfaceoftheplasticandimprovetheappearanceoftheplastic.(1)whenannealedplasticABSisformed,itiseasytoforminternalstressandeasytocrackatthestressconcentrationaftercoating.Annealingorsurfacetreatmentcanbeusedtoeliminatestress.AnnealingtreatmentistoheattheABSplasticmoldingpartsbelowthethermaldeformationtemperature,thatis,60degreescentigrade,andheatpreservation2H.Inordertoreduceinvestmentinequipment,thewholesurfacetreatmentcanbeusedtoimprovethesurfacecondition.TheformulationandprocessofthewholesurfacetreatmentarelistedinTable1.Table1wholesurfacetreatmentformulaandprocessparameters/1water/3temperature/temperature/Croomtemperaturetreatmenttime/mi15-20(2)oilremovalABSplasticpartsareoftencontaminatedwithoil,handsweatanddemouldingagent,whichwillmaketheadhesionofthecoatingworse,thecoatingproducescracking,foamingandshedding.Oilremovalshouldbecarriedoutbeforecoating.ABSplasticpartsareusuallycleanedwithgasolineoralcoholandthenchemicaldegreasing.TheprocessformulaislistedinTable2.Table2theresidualalkalinesolutiononthesurfaceoftheworkpieceshouldbethoroughlycleanedaftertheprocessparametersofsodiumhydroxide(S/L)sodium50~70phosphate(S/L)20~30sodiumcarbonate(S/L)10~20surfaceactiveagent(S/L)5~10temperature/50~60treatmenttime/min10to15chemicaloil,andcleanedwithpurewater***,dryingordrying.(3)electricalanddustremovalplasticproductsareinsulators,andthesurfaceresistanceisgenerallyaround1013ohms,whichiseasytogeneratestaticelectricity.Aftercharged,itiseasytoadsorbtinydustintheairandsticktothesurface.Itisverydifficulttoremovedustfromelectrostaticadsorptionbygeneralblowingmethod.Highpressureionizedairflowhasgoodeffectinadditiontoelectrostaticprecipitator.PPEP540S╮PPEPKC10ZCPCˉ3025N2PPO/NH8006PC/EGN2030DFPP/ERC729DPCB-4110RPOMK300EWLCP杜邦5145LBK010PPL10G-00TPU58237PCKCG1020TPEE/E5674TPUˉ45APPA66美国杜邦FN718PC2456PPˉGC20S400PA66ˉRC006XXHPBTˉRS1430HDPE美国陶氏DGDK-3364TPUU-285ALPC/ABSC2950PC/144CPA66KN333G30EVA/7970HPA6BG-30XLCP3487-1EVAFL00206PBTˉCF40-08PC/ABSCF447PA66/HF3064G30EVAFF45PETGSKJN120PCˉB7110RPBT2000-OMSG452PC2458PMMA2010PPˉC5608PP/EP243REBA/***E768PCˉ500RSPBTˉ4815-BCBHDPELGME5500TPUˉD16N90UVThecommonmethodsofchemicalmodificationare:oneisoneelementofthemodifiedresinmonomer,themodifiedmonomerisanother,graftcopolymerizationinthereactionkettleandanewcopolymer.Thesecondmethodistomodifythemodifiedresinasthemainrawmaterialbyincreasingthepolarelementintheresinmolecule.聚丙烯广泛用于塑料管材的生产,但PP是一种抗老化性能差的材料,为了PP的性能,通过化学改性发明了PP-B和PP-R树脂。Polypropyleneiswidelyusedintheproductionofplasticpipes,butPPisakindofpooranti-agingmaterial.InordertoimprovetheperformanceofPP,PP-BandPP-Rresinhebeeninventedbychemicalmodification.PP-B树脂是丙烯和的嵌段共聚物。合成丙烯-嵌段共聚物要用两个聚合反应釜PP-Bresinisablockcopolymerofpropyleneandethylene.TwopolymerizationreactorsforthesynthesisofpropyleneethyleneblockcopolymersPA66对许多溶剂具有抗溶性,但对酸和其它一些氯化剂的抵抗力较弱。PA66isresistanttomanysolvents,butislessresistanttoacidsandotherchlorinatedagents.工艺条件processconditi***干燥处理:如果加工前材料是密封的,那么就没有必要干燥。然而,如果储存容器被打开,那么建议在85℃的热空气中干燥处理。如果湿度大于0.2%,还需要进行105℃,12小时的真空干燥。熔化温度:260~290℃。对玻璃添加剂的产品为275~280℃。熔化温度应避免高于300℃。模具温度:建议80℃。模具温度将影响结晶度,而结晶度将影响产品的物理特性。对于薄壁塑件,如果使用低于40℃的模具温度,则塑件的结晶度将随着时间而变化,为了保持塑件的几何性,需要进行退火处理。***压力:通常在750~1250bar,取决于材料和产品设计。Drying:ifthematerialissealedbeforeprocessing,thereisnoneedtodry.However,ifthestoragecontainerisopened,itisrecommendedtodryat85Chotair.Ifthehumidityisgreaterthan0.2%,thevacuumdryingat105Cand12hoursisrequired.Meltingtemperature:260~290C.Theproductofglassadditiveis275~280C.Themeltingtemperatureshouldbeoidedabove300degreesC.Moldtemperature:recommended80degreesC.Themoldtemperaturewillaffectthecrystallinity,andthecrystallinitywillaffectthephysicalcharacteristicsoftheproduct.Forthin-walledplasticparts,ifthemoldtemperaturebelow40degreesisused,thecrystallinityoftheplasticpartswillchangewithtime.Inordertomaintainthegeometricstabilityoftheplasticparts,theannealingprocessisneeded.Injectionpressure:usuallyin750~1250bar,dependingonmaterialandproductdesign.***速度:高速(对于增强型材料应稍低一些)。高性能PC‖/ABSA2200合金材料具有高抗冲击、优良的耐候性和亚光效果,可应用于车载音响和DVD、汽车仪表板等部件。电镀级PC‖/ABSA2200MP具有杰出的电镀效果和良好的耐低温性能,可应用于汽车把手等电镀部件。Injectionspeed:highspeed(forenhancedmaterialshouldbeslightlylower).HighperformancePC/ABSA2200alloymaterialhashighimpactresistance,excellentweatherabilityandsublighteffect.Itcanbeusedinvehicleaudio,DVDsystem,vehicledashboardandothercomponents.ElectroplatedgradePC/ABSA2200MPhasexcellentelectroplatingeffectandgoodlowtemperatureresistance.Itcanbeappliedtoelectroplatingpartssuchascarhandles.注意事项:/PC‖塑料成型问题Note:/PCplasticsmoldingprocessproblem??产生原因及解决办法CausesandSoluti***??1、银丝1,silversilk??a、原材料受潮————干燥原料A,rawmaterialsaredampened-dryrawmaterials??b、树脂过热分解————减低成型温度B,superheateddecompositionofresin--reducingmoldingtemperature??c、螺杆压缩比小,背压不足————背压C,screwcompressionratiois***all,backpressureisinsufficient--increasebackpressure.??d、模温过低————加热模具D,lowmoldtemperature--heating??e、排气不良————模具分型面开排气槽Eandpoorexhaust--theexhaustmanifoldofthemoldpartingsurfacePPEP540S╮PPEPKC10ZCTPU/122PPS6345L4PA61013G-15PPSFZ-3805-A1PPS-hGR30PC/ABS德国科思创(拜耳)T45PGPP/XM3T08PC/ET311A6V30H1.0PA66美国杜邦HTN53G50LRHFEVALD-316PA6SEGM35H1PPˉAP03BPA66FR-10PP/1125NAPA66GF40-02POM可隆K900PP/AE716BCPC1414PA66ST-801HSPPˉ4663ˉPC/PET基础创新塑料CL100BPPRA1E10hLDPE中石化燕山HM1-I7.0PP95610CSU10PA12法国阿科玛G-350PPE/RTP1781AESHW600FREVA/C250PPO旭化成201Z3X32264PPPD402PP宁波台塑3080PP1572PPS东曹P-01PBTWEF32ISPPPSZ-650-T6ˉPCˉVRY2500PA6ˉV130H2.0PA6ˉB001POE875LAS/92HRTPU5714PC/ABSLG9000KJ)