ABSresinisoneofthefivemajorsyntheticresins.Itisresistanttoimpact,heatresistance,lowtemperatureresistance,chemicalresistanceandelectricalproperties.Italsohasthecharacteristicsofeasyprocessing,stablesize,goodglossandsoon.Itiseasytopaint,coloring,andcanalsobeusedforsurfacesprayingmetal,electroplating,welding,hotpressingandbonding,andsoon.Secondaryprocessing,widelyusedinmechanical,automotive,electronicandelectricalappliances,instruments,textilesandarchitectureandotherindustrialfields,isaverywidelyusedthermoplasticengineeringplastics.Acrylonitrilebutanestyrenecopolymerisathreecomponentcopolymerc***istingofacrylonitrile,butaneandstyrene.ABSAX4200,ABSAXT010,ABSAXT040,ABSAF3800,ABSAT5800,ABSAXTO4O,Dan,andYang,①热塑性弹性体TPR热塑性弹性体TPR，TPE是一种具有橡胶的高弹性，度，高回弹性，又具有可注塑加工的特征，具有环保，硬度范围广，有优良的着****，触感，耐候性，***性和耐温性，加工性能优越，无须硫化，可以循环使用成本，既可以二次注塑成型，与PP、PE、PC‖、PS、ABS等基体材料粘合，也可以单独成型。热塑性弹性体既具有热塑性塑料的加工性能，又具有硫化橡胶的物理性能，可谓是塑料和橡胶优点的优势组合。热塑性弹性体正在大肆原本只属于硫化橡胶的领地。近十余年来，电子电器、通讯与汽车行业的快速发展带动了热塑性弹性体市的高速发展。(1)thermoplasticelastomerTPRthermoplasticelastomerTPR,TPEisakindofrubberwitPC台化AC2820-ALABSMP-0160RPP/PT8N1PBTCA7200NXPBTˉPF329G4PPˉ20MBT666TPUˉTE85APPOMLX-30BKEVA住友化学SV210PBT宝理330HR-ED3002TPU德国巴斯夫60APPˉJ-590KPC/HP1PCDC-006POM德国赫斯特C9021SPP1100RCLCP宝理E480iVF2201POM基础创新塑料KFL-4416PPAW564PP/M-350UNLCP/7145L/PPMFX-1008HSPBTˉ1300APA123030UPPO三菱工程AN60-9001PA12/E-55TPV美国埃克森美孚8621-60PP三井化学BC2ZBPPMV00ASXPTPE美国吉力士G7950-1PA12/AZM15TLDPBT东丽1201G15BKPP/BE961MOPC/ABS/EMI2583hhighelasticity,highstrength,highresilience,andhasthecharacteristicsofinjectionmolding.Ithasenvironmentalprotectionandnon-toxicsafety,awiderangeofhardness,hasexcellentwear,soft,weatherability,fatigueresistanceandtemperatureresistance,excellentprocessingperformance,neednot.Vulcanization,canberecycledtoreducecosts,canbetwoinjectionmolding,andPP,PE,PC,PS,ABSandothermatrixmaterialscoatedandbonded,alsocanbeindividuallymolded.Thermoplasticelastomersnotonlyhetheprocessingpropertiesofthermoplastic,butalsohethephysicalpropertiesofvulcanizedrubber,whichistheadvantagecombinationofplasticsandrubber.Thermoplasticelastomersareoccupyingtheterritoriesthatwereoriginallyvulcanizedrubber.Overthepasttenyears,therapiddevelopmentofelectronic,electrical,communicationandautomotiveindustrieshasledtotherapiddevelopmentofthethermoplasticelastomermarket.S主要用于橡胶制品、树脂改性剂、粘合剂和沥青改性剂四大应域。在橡胶制品方面，S模压制品主要用于制鞋（鞋底）工业，挤出制品主要用于胶管和胶带；作为树脂改性剂，少量S分别与聚丙烯（PP）、聚（PE）、聚苯（PS）共混可明显制品的低温性能和冲击强度；Sismainlyusedinrubberproducts,resinmodifiers,adhesivesandasphaltmodifiersfourmajorareas.Inrubberproducts,Smoldingproductsaremainlyusedintheindustryofshoe(sole).Theextrudedproductsaremainlyusedforrubbertubeandadhesivetape.Asaresinmodifier,a***allamountofSblendwithpolypropylene(PP),polyethylene(PE)andpolystyrene(PS),respectively,toimprovethelowtemperatureperformanceandimpactstrengthoftheproducts.PA6A1022GFL60TPEEˉ5720EVA/RS-1717PA11/BECNTLPC143R-111PBT基础创新塑料***GF30PBT/PET/SG5300/PBTVX5011PPˉGP3202PA66美国杜邦70G43LBK031PA66RFN18SXZPA12RD302G6PC/IV2200PCSLX9271TPPA/UF00BASTPEBT-3028DTPU54601CPE美国盛禧奥（斯泰隆）702PPA66上海赛璐珞SG1-31-35PP/EKS157DNATPPˉY-130TPE1045BM|8901PA6670G30HSLRPA66/A30N02TPEˉ3055DˉPCˉGN-3610ZLPP/EP380TPOE/8025HCPBT/1401X04/PC/CXT17GPPS高福GPS-525NPP/EP648VHDPE中石油独山子T60-800PP/TRC104NG13031PP-R是以共聚PP为基础经改性而成的无规聚丙烯。无规PP的分子量***小的只有几万，内聚力小，熔，机械性能差。只有经过改性的无规PP才有实际应用价值。其改性是将丙烯气化后用气相法送入反应釜，并用气锁将材料从DI一反应釜送到第二反应釜，并在第二反应釜中加入。采用高活性、高选择性的丙烯催化剂，加在反应釜的上部，靠搅拌将其均匀地分散到粉料层上，通过控制与丙烯的比例形成无规共聚物。这种聚合物改变了PP分子链的构型，使在PP的分子链上随机而均匀地聚合。PP-RisanatacticpolypropylenemodifiedbyethylenebasedoncopolymerizationPP.ThemolecularweightofrandomPPisonlytensofthousandsof***,***allcohesion,lowmeltingpointandpoormechanicalproperties.OnlytherandomPPmodifiedbyethylenehaspracticalapplicationvalue.Themodificationprocessistovaporizedpropyleneintoareactorbygasphasemethod,andusegaslocksystemtosendmaterialfromDIreactortosecondreactionkettleandaddethyleneinthesecondreactionkettle.Thehighactivityandhighselectivitypropylenecatalyst,addedtotheupperpartofthereactor,isevenlydispersedintothepowderlayerbymixing,andtherandomcopolymerisformedbycontrollingtheproportionofethylenetopropylene.ThepolymerchangedtheconfigurationofPPchainandmadeethylenepolymerizerandomlyandevenlyonthemolecularchainofPP.与普通PP相比，PP-R材料的耐应力开裂性极大，在温度和内外压力作用下，其性能衰减非常，是目前用作生产输送冷热水管的***为的材料之一。ComparedwiththeordinaryPP,thestresscrackingresistanceofthePP-Rmaterialisgreatlyimproved.Undertheactionoftemperatureandinternalandexternalpressure,itsperformanceattenuationisveryslow.Itisoneoftheidealmaterialsusedtoproduce***fortheproductionandtransportationofcoldandhotwaterpipes.PA66（聚酰胺66或尼龙66），同PA6相比，PA66更广泛应用于汽车工业、仪器壳体以及其它需要有抗冲击性和度要求的产品。聚酰胺树脂，英文名称为polyamide，简称PA。俗称尼龙(Nylon)，它是大分子主链重复单元中含有酰胺基团的高聚物的总称。为五大工程塑料中产量***大、品种***多、用途***广的品种。尼龙中的主要品种是尼龙6和尼龙66，占jue对主导地位，中文名称尼龙66外文名Polyamide66又称尼龙66缩写nylon66CAS编号32131-17-2成分聚己二酰己二胺适用范围机械、汽车、电气装置的零件PA66(polyamide66ornylon66),comparedwithPA6,ismorewidelyusedintheautomotiveindustry,theshelloftheinstrument,andotherproductsthatrequireimpactresistanceandhighstrength.Polyamideresin,theEnglishnameispolyamide,orPA.CommonlyknownasNiron(Nylon),itisageneraltermforpolymerscontainingmacrocyclicbackbonechainscontainingamidegroups.Itisavarietyoffivemajorengineeringplasticswhichyield***,***and***.Themainvarietiesofnylonarenylon6andnylon66,leadingtoJue,Chinesenamenylon66foreignnamePolyamide66,nylon66abbreviatednylon66CAS32131-17-2componentpoly(twoacyl)adipaminesuitableformechanical,automotive,electricalequipmentpartsPA6的化学物理特性和PA66很相似，然而，它的熔点较低，而且工艺温度范围很宽。它的抗冲击性和抗溶解性比PA66要好，但吸湿性也更强。因为塑件的许多品质特性都要受到吸湿性的影响，因此使用PA6设计产品时要充分考虑这一点。为了PA6的机械特性，经常加入各种各样的改性剂。玻璃纤维就是***常见的添加剂，有时为了抗冲击性还加入合成橡胶，如EPDM和R等。对于没有添加剂的产品，PA6的收缩1%到1.5%之间。加入玻璃纤维添加剂可以使收缩率到0.3%（但和流程相垂直的方向还要稍高一些）。成型组装的收缩率主要受材料的结晶度和吸湿性影响。实际的收缩率还和塑件设计、壁厚及其它工艺参数成函数关系。ThephysicalandchemicalpropertiesofPA6aresimilartothoseofPA66.However,itsmeltingpointislowandthetemperaturerangeoftheprocessisverywide.ItsimpactresistanceandsolubilityarebetterthanthatofPA66,butitshygroscopicityisstronger.Becausemanyqualitycharacteristicsofplasticpartsareaffectedbyhygroscopicity,weshouldgivefullc***iderationtothiswhenusingPA6todesignproducts.InordertoimprovethemechanicalpropertiesofPA6,variousmodifiersareoftenadded.Glassfiberisacommonadditivefor***.Sometimessyntheticrubber,suchasEPDMandR,isaddedinordertoimproveitsimpactresistance.Forproductswithoutadditives,PA6shrinksbetween1%and1.5%.Addingglassfiberadditivescanreducetheshrinkagerateto0.3%(butslightlyhigherinthedirectionperpendiculartotheprocess).Theshrinkageofmoldingandassemblyismainlyaffectedbythecrystallinityandmoistureabsorptionofthematerial.Theactualshrinkagerateisalsorelatedtoplasticdesign,wallthicknessandotherprocessPPˉ2120GPA66德国巴斯夫A3EG6BK00564PC/ABSC6300PC/3022IR-HDEVA4030ACPPˉ9059TPEPB-575POMN2650-Z4LEVPA12/CX7323PBT/PET德国巴斯夫B4040G4PCˉ2060-6PC/EM3110PP/951CDFL32PPBTJ600PP505PPA66美国杜邦73G30HSLBK416PC基础创新塑料HPX4PA46荷兰DMC50BKPP辽宁华锦化工SP179PC/ABST65PGPOM宝理M450UHMWPE511A6ˉ8332GPA12SF006PP中石化茂名K9017HPC945PC/ABS/NS0031/PP油化9310PP1920PA66基础创新塑料RC-1004PA6ˉ1325GVSTPU/RxT65DPA66基础创新塑料R2000A)